Recent Publications

  1. Lam, Edmond; Browning, C. Scott; Yu, Joanne O.; Farrar, David H.; Sereda, Julie L.; Rampersad, Nicole C. "Indolylphosphine derivatives as transition metal ligands." Can. Pat. Appl. (2006).

  2. Consorti, Crestina S.; Suarez, Paulo A. Z.; De Souza, Roberto F.; Burrow, Robert A.; Farrar, David H.; Lough, Alan J.; Loh, Watson; Da Silva, Luis H. M.; Dupont, Jairton. "Identification of 1,3-Dialkylimidazolium Salt Supramolecular Aggregates in Solution." Journal of Physical Chemistry B (2005), 109(10), 4341-4349.

  3. Babij, Claudia; Farrar, David H.; Koshevoy, Igor O.; Poe, Anthony J.; Tunik, Sergey P. "Kinetic studies of some substituted hexarhodium carbonyl clusters." Dalton Transactions (2005), (1), 116-122.

  4. Joanne O. Yu, Edmond Lam, Julie L. Sereda, Nicole C. Rampersad, Alan J. Lough, C.S. Browning, David H. Farrar. "2-Indolylphosphines: A New Class of Tunable Ligands – Their Synthesis, Facile Derivatization, and Coordination to Pd(II)" Organometallics (2005), 1, 37-47.

  5. Lam, Edmond; Farrar, David H.; Browning, C. Scott; Lough, Alan J. "Reactions of 2-indolylphosphines with Ru3(CO)12: cluster capping with m3,h2-indolylphosphine as an anionic six-electron P,N-donor ligand." Dalton Transactions (2004), 20, 3383-3388.

  6. Arnanz, Avelina; Marcos, Maria-Luisa; Moreno, Consuelo; Farrar, David H.; Lough, Allan J.; Yu, Joanne O.; Delgado, Salome; Gonzalez-Velasco, Jaime. "Synthesis, structures and comparative electrochemical study of 2,5-bis(trimethylsilylethynyl)thiophene coordinated cobalt carbonyl units." Journal of Organometallic Chemistry (2004), 689(20), 3218-3231.

  7. Farrar, David H.; Grachova, Elena V.; Haukka, Matti; Heaton, Brian T.; Iggo, Jonathan A.; Pakkanen, Tapani A.; Podkorytov, Ivan S.; Tunik, Sergey P. "The structure and dynamic behaviour of disubstituted derivatives of [Rh6(CO)16] containing bidentate phosphorus ligands." Inorganica Chimica Acta (2003), 354, 11-20.

  8. Tunik, Sergey P.; Khripoun, Vassily D.; Balova, Irina A.; Borovitov, Maxim E.; Domnin, Ivan N.; Nordlander, Ebbe; Haukka, Matti; Pakkanen, Tapani A.; Farrar, David H. "Reactions of [H2Os3(CO)10] with Conjugated Diynes (RC2C2R') Containing Nucleophilic Oxygen in b Position of a Substituent (R = Ph, R' = CH2OH, C(O)Ph; R = R' = CMe2(OH))." Organometallics (2003), 22(17), 3455-3465.

  9. Bunten, Kevin A.; Farrar, David H.; Poe, Anthony J. "Potential Energy Surfaces in Transition States for Associative Reactions of Metal Carbonyl Clusters: Reactions of Rh4(CO)12 with P-Donor Nucleophiles." Organometallics (2003), 22(17), 3448-3454.

  10. Tunik, Sergey P.; Koshevoy, Igor O.; Poe, Anthony J.; Farrar, David H.; Nordlander, Ebbe; Haukka, Matti; Pakkanen, Tapani A. "Chiral hexarhodium carbonyl clusters containing heterobidentate phosphine ligands; a structural and reactivity study." Dalton Transactions (2003), (12), 2457-2467.

  11. Burrow, Robert A.; Morel, Ademir F.; Graebner, Ilmar B.; Lough, Alan J.; Farrar, David H. "Absolute configuration of diacetylated acrenol as its chloroform solvate." Acta Crystallographica, Section E: Structure Reports Online (2003), E59(3), o350-o352.

  12. Burrow, Robert A.; Morel, Ademir F.; Graebner, Ilmar B.; Farrar, David H.; Lough, Alan J. "The acetyl derivative of humirianthol." Acta Crystallographica, Section E: Structure Reports Online (2003), E59(3), o347-o349.

  13. Burrow, Robert A.; Facco, Janaina T.; Lang, Ernesto S.; Farrar, David H.; Lough, Alan J. "Trans-dichloro(dimethyl sulfide-kappa S)(pyridine-kappa N)platinum(II)." Acta crystallographica. Section C, Crystal Structure Communications (2004 Jan), 60(Pt 1), m7-9.

  14. Kevin A. Bunten, David H. Farrar, Anthony J. Poë and Alan Lough, (2002) "Stoichiometric and Catalytic Oxidation of BINAP by Dioxygen in a Rh(I) Complex", Organometallics, 21, 3344-3350.

  15. S.P. Tunik, I. Koshevoy, C. Babij, C.S. Browning, D.H. Farrar, A.J. Poë, and I.S. Podkorytov, (2002) "Synthesis, X-ray Crystal Structure and Fluxional Behavior of Rh6(CO)14(m2-P(NC4H4)3) Cluster", J. Amer. Chem. Soc., 124, 8922-8931.

  16. Dupont, J.; Ebeling, G.; Delgado, M. R.; Consorti, C. S.; Burrow, R.; Farrar, D. H.; Lough, A. J. "A palladium complex containing a new C2-symmetric bidentate non-racemic oxalamidine ligand: synthesis and catalytic properties", Inorg. Chem. Comm., (2001), 4, 471-474.

  17. David H. Farrar, Alan Lough, Charles Patirana, Anthony J. Poë, Sergey P. Tunik and Elena V. Grachova, (2001) "Ligand effects on the structures of Rh6(CO)15L clusters", J. Chem. Soc. Dalton, 2015-2019.

  18. C. Moreno, M.-L. Marcos, G. Domínguez, A. Arnanz, D.H. Farrar, R. Teeple, A. Lough, J. González-Velasco and S. Delgado (2001) "Synthesis and Electrochemical Study of Aromatic Ethynylcobalt Complexes with Electronic Communication", J. Organomet. Chem., 631, 19-28.

  19. R.A. Burrow, D.H. Farrar, A.J. Lough, M.R. Siqueira and F. Squizani (2000) "Phenylphosphinic acid", Acta Cryst., C56, e357-e358.

  20. K.A. Bunten, D.H. Farrar, A.J. Poë, and A.J. Lough, (2000) "Chelation Kinetics of Some Bidentate Phosphine Ligands on Penta-Coordinate Ru Carbonyl Complexes", Organometallics, 19, 3674-3682.

  21. K.A. Bunten, D.H. Farrar, and A.J. Lough, (2000) "Structure of (R)-(+)-2,2'-Bis(diphenylphosphonyl)-1,1'-binaphthyl", Acta Cryst., C56, e267-e268.

  22. D.H. Farrar, A.J. Poë and Y. Zheng, (2000) "Kinetic and Thermodynamic Studies of Reversible Adduct Formation Between Ru5C(CO)15 and Acetonitrile", Inorg. Chim. Acta, 300-302, 668-674.

  23. C. Moreno, J.L. Gómez, A. Lough, R. Medina, M.J. Macazaga, D.H. Farrar and S. Delgado, (1999) "Synthesis and characterization of new transition-metal diynyl complexes", J. Organomet. Chem., 579, 63-74.

  24. D.H. Farrar, A.J. Poë and R. Ramachandran, (1999) "Exceptional substitutional lability of the "raft" cluster Os6(CO)20NCMe", J. Organomet. Chem., 573, 217-224.

  25. C. Moreno, M.L. Marcos, M.J. Macazaga, R.M. Medina, D.H. Farrar and S. Delgado, (1998) "New Procedure for Synthesis of (Fulvalene)Ditungsten Carbonyl Halides and Cyclopentadienyltungsten Carbonyl Halide Complexes with P-donor Nucleophiles", Organometallics, 17, 3733-3738.

  26. C. Moreno, M.L. Marcos, M.J. Macazaga, R.M. Medina, D.H. Farrar, J. González-Velasco and S. Delgado, (1998) "New General Synthetic Strategy of Fulvalene Homodinuclear Zwitterions. Electrochemical Evidence for Electronic Communication in (h5 :h5-(C5H3CO2Me)2) Mo2(CO)6I2.", Organometallics, 17, 4657-4665.

  27. R.A. Burrow, D.H. Farrar, J. Hoa, A. Lough, O. Mourad, A.J. Poë and Y. Zheng, (1998) "Structural studies on substituted pentaruthenium carbido carbonyl clusters", Polyhedron, 17, 2907-2919.

  28. C.S. Browning, R.A. Burrow, D.H. Farrar and H.A. Mirza, (1998) "Synthesis, Characterization and Reactivity of Bis(diphenylphosphino)amine Nickel Complexes", Inorg. Chim. Acta, 271, 112-118.

  29. D.H. Farrar, A.J. Poë, R. Ramachandran and C. Moreno, (1998) "Steric limitations in associative substitution reactions of Os3(CO)9(m-C4Ph4)", Inorg. Chim. Acta, 274, 82-89.

  30. Y. Dohta, C.S. Browning, P. Rekonen, M. Kodaka, T. Okada, K. Okamoto, R. Natale, C. Yip, D.H. Farrar, and H. Okuno, (1997) "Preparation, Structure and cytotoxicity of cis-diammineplatinum(II) dinuclear complexes with 1-alkyluracil and imidate Ligands", Inorg. Chim. Acta, 263, 69-79.

  31. D.H. Farrar, J. Hao, O. Mourad and A.J. Poë (1997) "Substituent Effects on Associative Reactions of the Cluster Ru5C(CO)14L (L = P(OPh)3 and P(C6H11)3 with P-donor Nucleophiles", Organometallics, 16, 5015-5022.

  32. D.H. Farrar, J. Hao, A.J. Poë and T.A. Stromnova, (1997) "The Aryl Effect in Disubstituted Dimanganese and Dicobalt Carbonyls", Organometallics, 16, 2827-2832.

  33. C.S. Browning, D.H. Farrar and D.C. Frankel, (1997) "Crystal Structure of
    Ag2[(PPh2)2NMe)2(THF)2][BF4]2", Zeit. für Kristallographie (NCS), 212, 201-202.

  34. C.S. Browning, D.H. Farrar, D.C. Frankel and J.J. Vittal, (1997) "Synthesis, Characterization and Reactivity of Binuclear Palladium(I) Bis(diphenylphosphino)amine Complexes", Inorg. Chim. Acta, 254, 329-338.

  35. J. Granifo, M.E. Vargas, E.S. Dodsworth, D.H. Farrar, S.S. Fielder and A.B.P. Lever, (1996) "Mononuclear and Dinuclear Complexes of Molybdenum Carbonyl Derivatives with 2-Pyridylaldazine and Phosphines. Syntheses, Structure, Spectroscopic and Electrochemical Characterisation and Solvatochromic Effects", J. Chem. Soc. Dalton, 4369-4378.

  36. S. Delgado, M.J. Macazaga, R. Medina, C. Moreno, J. González-Velasco, M.L. Marcos, D.H. Farrar and R. Ramachandran, (1996) "Synthesis, Reactivity, Electrochemical Study and Crystal Structures of (h5: h5 -(C5H3CO2Me)2Mo2(CO)6", Organometallics, 15, 5416-5424.

  37. C.S. Browning, T.E. Burrow, D.H. Farrar and A.J. Lough (1996) "2,2'-Methylenebis[5,5-dimethyl-2,2'-dioxide]1,3,2-dioxaphosphorinane", Acta Cryst., C52, 652-654.

  38. C.S. Browning, D.H. Farrar and D.C. Frankel, (1996) "Preparation, Characterization and Crystal Structure of Fe((OPPh2)2N)3", Inorg. Chim. Acta, 241, 111-115.
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