University of Toronto
Stephan Research Group

1989

47. T.A. Wark, D.W. Stephan, Early Metal Thiolato Species as Metalloligands in the Formation of Early/Late Heterobimetallics: Syntheses and Molecular Structures of Cp2Ti(SMe)2, Cp2V(SMe)2,  (Cp2Ti(µ-SMe)2)2Ni and (Ni(µ-SMe)2)2, Organometallics 8, 2836-2843.

46. P.Y. Zheng, D.W. Stephan, Diphosphido-Bridged Early/Late Heterobimetallic Complexes: Synthesis and Molecular Structure of Cp2Zr(µ-PPh2)2ReH(CO)3, Can. J. Chem. 67, 1584-1589.

45. P.Y. Zheng, T.T. Nadasdi, D.W. Stephan, Monophosphido-Bridged Early/Late Heterobimetallic Complexes: Cooperative Activation of CO, Organometallics 8, 1393-1398.

44. D.W. Stephan, Early-Late Heterobimetallics, Coord. Chem. Rev. 95, 41-109.

43. H.A. Jenkins, S.J,. Loeb, D.W. Stephan, Synthesis and Reaction Chemistry of the Coordinatively Unsaturated Heterobimetallic Complexes (CO)3(PPh3)Fe(µ- PCy2)Rh(PPh3)(CO) and (CO)4Fe(µ-PCy2)Rh(COD). Crystal and Molecular Structure of (CO)3(PPh2)Fe(µ-PCy2)Rh(PPh3)(CO), Inorg. Chem. 28, 1998-2003.

42. S.J. Brown, P.K. Mascharak, D.W. Stephan, Synthetic Analogue Approach to Copper (II) Bleomycin, Inorg. Chem. 28, 468-477.

1988

41. L. Gelmini, D.W. Stephan, (Ph3P)2Rh(ŋ2-SPCY2): A Complex Containing a Side-On Bonded, ŋ2 -Secondary Phosphine Sulfide Anion, Can. J. Chem. 66, 2647-2651.

40. W. Zheng, D.W. Stephan, Titanium-Tin Complexes: Synthesis and Structure of Cp2Ti(SnPh3)Cl, Inorg. Chem. 27, 2386-2388.

39. S.J. Brown, P.K. Mascharak, D.W. Stephan, Characterization of a Crystalline Synthetic Analogue of Copper (II) Bleomycin, J. Am. Chem. Soc. 110, 1996-1997.

38. S.J. Brown, X. Tao, T.A. Wark, D.W. Stephan, P.K. Mascharak, Synthetic Analogue Approach toMetallobleomycins 4. A New Halo-bridged Dimeric and Polymeric (Infinite Zigzag Chain) Complexes of Copper (II) with Peptide Ligands Related to Bleomycins, Inorg. Chem. 27, 1581-1587.

37. P.A. Seewald, G.S. White, D.W. Stephan, Cationic Titanium (III) Complexes: Phosphine Substitution Reactions, Can. J. Chem. 66, 1147-1152.

36. G.S. White, D.W. Stephan, Synthesis, Electrochemistry, Reactivity and Structural Studies of the Early/Late Transition Metal Heterobimetallic Complex [Cp2Ti(µ-SCH2CH2CH2PPh2)2Ni], Organometallics 7, 903-910.

35. L. Gelmini, D.W. Stephan, Preparation, Reactivity, Hydroformylation Catalysis and Structural Studies of the Early Transition Metal/Late Transition Metal Heterobimetallic Complexes Cp2M(µ-PR2)2M'H(CO)PPh3 (M = Zr, Hf; M' = Rh, Ir), Organometllics 7, 849-855.

1987

34. S.G. Rosenfield, M.Y.L. Wong, D.W. Stephan, P.K. Mascharak, Synthesis, Structure and Properties of Tetraphenylphosphonium tetrakis (2-mercaptopropinoato)- trinickel (II) (Ph4P)2[Ni3(µ-SCH(CH3)COO)4]: A Linear Trimeric Thiolato Complex of Nickel, Inorg. Chem. 26, 4119-4122.

33. G.S. White, D.W. Stephan, Synthesis and Structural Studies of the Ti-Rh Heterobimetallic Complexes: Characterization and Electrochemistry of the Redox Partners [Cp2Ti(µ- SCH2CH2CH2PPh2)2Rh]BF4 and [Cp2Ti(µ-SCH2CH2CH2PPh2)2Rh]0, Organometallics 6, 2169-2175.

32. L. Gelmini, H.P. Berends, D.W. Stephan, S.G. Rosenfield, P.K. Mascharak,  New Octahedral Thiolato-Complexes of Divalent Nickel: Synthesis, Structure and Properties of (Et4N)[Ni(SC5H4N)3] and (Ph4P)[Ni(SC4H3N2)3]CH3CN, Inorg. Chem. 26, 2792-2797.

31. L. Gelmini, D.W. Stephan, Synthesis, Characterization and Chemistry of Titanium(IV), Titanium(III), Zirconium(IV) and Hafnium(IV) Complexes of Phosphine Sulfides and Selenides. The Crystal and Molecular Structures of Cp2Ti(SPCY2)2, Cp2Ti(S2PCY2) and Cp2Ti(Se2PPh2), Organometallics 6, 1515-1522.

30. X. Tao, D.W. Stephan, P.K. Mascharak, Synthetic Analogues to Metallobleomycins 2. Synthesis, Structure and Properties of the Low-Spin Iron (III) Complex of N-(2-(4- Imidazolyl)ethyl)pyridine-2-carboxamide, Inorg. Chem. 26, 754-759.

29. A.P. Hitchcock, D.W. Stephan, EXAFS Studies of [N(C2H5)4]2[M(SC6H5)4] and [N(C2H5)4]2[M4(SC6H5)10], M = Zn, Cd: Model Compounds for Zn and Cd Metallothioneins, Inorg. Chim. Acta. 136, L1-L5.

28. T.A. Wark, D.W. Stephan, Synthesis, Characterization and Structural Studies of Thiolato- bridged Titanium(IV)-Copper(I) Species: Heterobimetallic Complexes Containing d10-d0 Dative Bonds, Inorg. Chem. 26, 363-369.

27. H.P. Berends, D.W. Stephan, Towards Cu(II) Hemocyanin Models Part 2: The Synthesis and Characterization of BinuclearCopper(II) Complexes of a Heptadentate Ligand. Inorg. Chem. 26, 749-754.

26. T.W. Obal, C.J. Willis, D.W. Stephan, R.T. Boere, D. Esser, Complexes of Hybrid Ligands: The Synthesis of a Thioanisole Substituted Fluor-Alcohol and its Complexes with Pd(2+) and Pt(2+); The Structure of a Palladium(II) Complex Containing Alkoxide, Phosphine, Thioether and Chloride Donors, Can. J. Chem. 65, 798-803.

1986

25. S.J. Brown, X. Tao, P.K. Mascharak, D.W. Stephan, Synthetic Analog Approach to Metallobleomycin, Part 1: Synthesis, Structure and Properties of the Copper Complexes of Two Peptides Related to Bleomycin, Inorg. Chem. 25, 3377-3384.

24. L. Gelmini, D.W. Stephan, The Preparation, Characterization and Reactivity of the Early- Transition Metal/Late Tranisition Metal Heterobimetallic Complexes: Cp2Zr(µ-PPh2)2MLN M= Ni, Pd and Pt, Inorg. Chem. 25, 1222-1225.

23. L. Gelmini, D.W. Stephan, The Facile Synthesis of Early- Transition Metal/Late- Transition Metal Heterobimetallic Complexes, (C5H5)2Zr(µ-PPh2)2 as a Metalloligand for Ni, Pd and Pt, Inorg. Chim. Acta. 111, L17-L18.

22. D. Dick, D.W. Stephan, The Synthesis and Structural Studies of Rhodium Complexes of Phosphorus-Sulfur Ligands, Can. J. Chem. 64, 1870-1875.

21. L. Gelmini, D.W. Stephan, H.A. Taylor, S.J. Loeb, Heterobimetallic Dicyclohexylphosphido-bridged Complexes of MoNi, MoPt, WNi, WPd and WPt. Crystal and Molecular Structure of (CO)4Mo(µ-PCy2)2PdPPh3, Inorg. Chem. 25, 1977-1982.

20. E. Konefal, D.W. Stephan, S.J. Loeb, C.J. Willis, Coordination Modes of Polydentate Ligands 4. The Crystal and Molecular Structure of an Oxo-Bridged Iron(III) Complex Containing a Pentadentate Imino-Alkoxy Ligand, Inorg. Chim. Acta. 115, 147-151.

1985

19. H.P. Berends, D.W. Stephan, Towards a Hemocyanin Model: The Synthesis and Molecular Structure of a Binuclear Copper(II) Complex of a Heptadentate Ligand, Inorg. Chim. Acta. 99, L53-L56.

18. L. Gelmini, L.C. Matassa, D.W. Stephan, Heterobimetallic Complexes Part 2: Synthesis and Crystal and Molecular Structure of Cp3Zr(µ-PPh2)2Mo(CO)4, Inorg. Chem. 24, 2585-2588.

17. L. Gelmini, S.J. Loeb, D.W. Stephan, The Molecular Structure of Rh2Cl2(µ-CO)(µ-Ph2PCH2PPh2)2.2C6H6 A Rhodium 'A-Frame' Complex, Inorg. Chim. Acta. 98, L3-L6.

16. G.S. White, D.W. Stephan, Synthesis, Electrochemistry and Crystal and Molecular Structure of [Cp2Ti(µ-SCH2CH2PPh2)2Cu]BF4: A Heterobimetallic Species with a Copper to Titanium Dative Bond, Inorg. Chem. 24, 1499-1503.

15. E.M. Kinsch, D.W. Stephan, Synthesis an Crystal and Molecular Structure of MoS4(AuPEt3)2: A Linear Trinuclear Heterobimetallic Species, Inorg. Chim. Acta. 96, L87-L90.

14. R.T. Boere, W.M. Brown, D.W. Stephan, C.J. Willis, Coordination Modes of Polydentate Ligands Part 3, Five Coordinate Complexes of Co(II), Cu(II) and Ni(II) Containing a Tridentate Thioether-Alkoxy Ligand, Inorg. Chem. 24, 593-597.

1984

13. H.P. Berends, D.W. Stephan, Copper(I) and Copper(II) Complexes of Biologically Relevant Tridentate Ligands, Inorg. Chim. Acta. 93, 173-178.

12. D.W. Stephan, Iridium Complexes of Diphenylphosphinoethanethiol, Crystal and Molecular Structure of [IrH(SCH2CH2PPh2)(HSCH2CH2PPh2)(CO)]Cl: A New and Novel Example of Thiol Coordination, Inorg. Chem. 23, 2207-2210.

11. E.M. Kinsch, D.W. Stephan, A 31P Nuclear Magnetic Resonance and Fluorescence Study of the Interaction of an Anti-Arthritic Gold Phosphine Drug with Albumin, A Bioinorganic Approach, Inorg. Chim. Acta. 91, 263-267.

10. E. Konefal, S.J. Loeb, D.W. Stephan, C.J. Willis, Coordination Modes of Polydentate Ligands 1, The Template Synthesis of Complexes of Ni(II), Cu(II), Co(II) with Pentadentate and Hexadentate Ligands: The Structure of a Highly Distorted Six Coordinate Co(II) Complex, Inorg. Chem. 23, 538-545.

9. S.J. Loeb, D.W. Stephan, C.J. Willis, Coordination Modes of Polydentate Ligands 2, The Template Synthesis of Four-, Five- and Six- Coordinate Fluorinated Schiff-Base Complexes of Ni(II); The Structure of an Octahedral Ni(II) Complex Containing Two Tridentate Ligands, Inorg. Chem. 23, 1509-1512.

1983

8. D.W. Stephan, G.C. Papaefthymiou, R.B. Frankel, R.H. Holm, Analogues of the [4Fe-4S] Site of Reduced Ferredoxins: Structural and Spectroscopic Properties of [Et4N]3[Fe4S4(S-p- C6H4Br)4] in Crystalline and Solution Phases, Inorg. Chem. 22, 1550-1557.

1982

7. K.S. Hagen, D.W. Stephan, R.H. Holm, Metal Atom Exchange Reactions in Cage Molecules: The Systems [M4-nM'n(SPh)10]2-  M, M'= Fe(II), Co(II), Zn(II) and Cd(II) with Adamantane- Like Stereochemistry and the Structure of [(Fe4(SPh)10]2-, Inorg. Chem. 21, 3928-3936.

6. N.C. Payne, D.W. Stephan, Studies in Enantiomeric Discrimination 2: Incorporation of Chiral Amines in Chiral Platinum Complexes, Crystal and Molecular Structure of (Chloro)(Methyl)((+)-2S, 3S-isopropylidene-2, 3, -dihydroxy-bis- (diphenylphosphino)butane) Platinum (II), J. Organometal. Chem. 228, 203-215.

5. N.C. Payne, D.W. Stephan, Asymmetric Hydrosilation of Ketones Catalyzed by Rhodium Complexes Containing Chiral Chelate Ligands, Crystal and Molecular Structure of (Bicyclo[2. 2.1]hepta-2, 5, diene) [(S)-N, N-dimethyl-1-(0-9diphenylarsino)- phenyl) -ethylamine] Rhodium (I) Perchlorate, Inorg. Chem. 21, 182-188.

1981

4. N.C. Payne, D.W. Stephan, Studies in Enantiomeric Discrimination 1: Chiral Phosphine Complexes of Platinum, J. Organomet. Chem. 221, 223-230.

3. N.C. Payne, D.W. Stephan, The Preparation and 31P Nuclear Magnetic Resonance Studies of Platinum Complexes of Some Chiral Bidentate Phosphines, J. Organomet. Chem. 221, 203-221.

2. R.B. Bruce, D.W. Stephan, M.J. McGlinchey, Rearrangements of Sulfurimide Anions: 1, 4-bis(trimethylsilyl)-hexasulfurdiimide from Heptasulfurimide, Inorg. Chim. Acta. 53, L19-L20.

1980

1. N.C. Payne, D.W. Stephan, Preparation and 31P Nuclear Magnetic Resonance Studies of Chiral Phosphines, Can. J. Chem. 58, 15-21.

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