The ground state Ar-Br2 potential energy surface is predicted from
ab initio calculations and from an atom-atom model using empirical ArBr
potentials and the (evaluated ab initio) perturbation of the interaction
between Ar and Br within Br2. At all levels of modelling,
the surface has a
double-minimum topology, with a well for the linear (L) geometry in addition to
a well for the T-shaped geometry. This differs from the single-minimum topology
predicted by the commonly used pairwise additive Lennard-Jones potential. For
both ab initio and atom-atom model surfaces, the L-well is found to be
significantly deeper than the T-well; this relative behaviour is unchanged by
zero-point vibrations. Spectroscopic parameters are predicted for the present
surfaces. The final surfaces result from a scaling to reproduce the estimated
bond energy of the system. Possible reflections of the surface topology in
experimental observables are discussed.