New high-level ab initio calculations for ArI and ArI2 are reported and compared with experiments. For the directly calculated PES, the D0 values for both linear (L) and T-shaped conformers of ArI2 are found to be significantly larger (D0(L) = 197 and D0(T) = 181 cm-1) than deduced from recent experimental data. A further DIM-based correction in term of empirical diatomic potentials is successfully tested for ArCl2 and predicts for ArI2 the intervals D0(L) = 250±8 and D0(T) = 242±11 cm-1, matching earlier experimental results.