New high-level ab initio calculations for ArI and ArI2
are reported and compared with experiments.
For the directly calculated PES, the D0 values for both linear (L)
and T-shaped conformers of ArI2 are found to be significantly larger
(D0(L) = 197 and D0(T) = 181 cm-1)
than deduced from recent experimental data.
A further DIM-based correction in term of empirical diatomic potentials
is successfully tested for ArCl2 and predicts for ArI2
the intervals D0(L) = 250±8 and D0(T) = 242±11
cm-1, matching earlier experimental results.